C−H Activation/Borylation/Oxidation: A One-Pot Unified Route To Meta-Substituted Phenols Bearing Ortho-/Para-Directing Groups
Top Cited Papers
- 6 June 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (26), 7792-7793
- https://doi.org/10.1021/ja0349857
Abstract
An efficient one-pot C−H activation/borylation/oxidation protocol for the preparation of phenols is described. This method is particularly attractive for the generation of meta-substituted phenols bearing ortho-/para-directing groups, as such substrates are difficult to access by other phenol syntheses.Keywords
This publication has 6 references indexed in Scilit:
- A Stoichiometric Aromatic C-H Borylation Catalyzed by Iridium( I )/2,2′‐Bipyridine Complexes at Room TemperatureAngewandte Chemie-International Edition, 2002
- Synthesis and Structure of Formally Hexavalent Palladium ComplexesScience, 2002
- Regioselective Oxidation of Phenols to o-Quinones with o-Iodoxybenzoic Acid (IBX)Organic Letters, 2002
- Synthesis, Aggregation, and Adsorption Phenomena of Shape-Persistent Macrocycles with Extraannular Polyalkyl SubstituentsJournal of the American Chemical Society, 2001
- Alcohols, ethers and phenolsContemporary Organic Synthesis, 1997
- Chemistry of dioxiranes. 12. DioxiranesChemical Reviews, 1989