Improved Synthesis of Graphene Oxide
- 22 July 2010
- journal article
- Published by American Chemical Society (ACS) in ACS Nano
- Vol. 4 (8), 4806-4814
- https://doi.org/10.1021/nn1006368
Abstract
An improved method for the preparation of graphene oxide (GO) is described. Currently, Hummers’ method (KMnO4, NaNO3, H2SO4) is the most common method used for preparing graphene oxide. We have found that excluding the NaNO3, increasing the amount of KMnO4, and performing the reaction in a 9:1 mixture of H2SO4/H3PO4 improves the efficiency of the oxidation process. This improved method provides a greater amount of hydrophilic oxidized graphene material as compared to Hummers’ method or Hummers’ method with additional KMnO4. Moreover, even though the GO produced by our method is more oxidized than that prepared by Hummers’ method, when both are reduced in the same chamber with hydrazine, chemically converted graphene (CCG) produced from this new method is equivalent in its electrical conductivity. In contrast to Hummers’ method, the new method does not generate toxic gas and the temperature is easily controlled. This improved synthesis of GO may be important for large-scale production of GO as well as the construction of devices composed of the subsequent CCG.This publication has 43 references indexed in Scilit:
- Atomic Structure of Reduced Graphene OxideNano Letters, 2010
- The chemistry of graphene oxideChemical Society Reviews, 2009
- Fast and Facile Preparation of Graphene Oxide and Reduced Graphene Oxide NanoplateletsChemistry of Materials, 2009
- Atomic and Electronic Structure of Graphene-OxideNano Letters, 2009
- Synthesis of Water Soluble GrapheneNano Letters, 2008
- Detection of individual gas molecules adsorbed on grapheneNature Materials, 2007
- The rise of grapheneNature Materials, 2007
- Electronic Confinement and Coherence in Patterned Epitaxial GrapheneScience, 2006
- Study of oxygen-containing groups in a series of graphite oxides: Physical and chemical characterizationCarbon, 1995
- Preparation of Graphitic OxideJournal of the American Chemical Society, 1958