Use of Carbonaceous Polysaccharide Microspheres as Templates for Fabricating Metal Oxide Hollow Spheres

Abstract

A general method for the synthesis of metal oxide hollow spheres has been developed by using carbonaceous polysaccharide microspheres prepared from saccharide solution as templates. Hollow spheres of a series of metal oxides (SnO₂, Al₂O₃, Ga₂O₃, CoO, NiO, Mn₃O₄, Cr₂O₃, La₂O₃, Y₂O₃, Lu₂O₃, CeO₂, TiO₂, and ZrO₂) have been prepared in this way. The method involves the initial absorption of metal ions from solution into the functional surface layer of carbonaceous saccharide microspheres; these are then densified and cross‐linked in a subsequent calcination and oxidation procedure to form metal oxide hollow spheres. Metal salts are used as starting materials, which widens the accessible field of metal oxide hollow spheres. The carbonaceous colloids used as templates have integral and uniform surface functional layers, which makes surface modification unnecessary and ensures homogeneity of the shell. Macroporous films or cheese‐like nanostructures of oxides can also be prepared by slightly modified procedures. XRD, TEM, HRTEM, and SAED have been used to characterize the structures. In a preliminary study on the gas sensitivity of SnO₂ hollow spheres, considerably reduced “recovery times” were noted, exemplifying the distinct properties imparted by the hollow structure. These hollow or porous nanostructures have the potential for diverse applications, such as in gas sensitivity or catalysis, or as advanced ceramic materials.