Highly Efficient Atom Transfer Radical Addition Reactions with a RuIII Complex as a Catalyst Precursor
- 23 May 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (23), 7440-7441
- https://doi.org/10.1021/ja0617542
Abstract
The combination of the air-stable RuIII complex [Cp*RuCl2(PPh3)] with AIBN can be used to catalyze the atom transfer radical addition reactions of polychlorinated compounds and of sulfonyl chlorides to olefins with unprecedented turnover numbers of up to 44 000.Keywords
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