Preparation of Lagt Ans Via Oxidation of Cyclic, Tertiary and Secondary Amines with Hg(II)-Edta Complex in Alkaline Medium
- 1 August 1988
- journal article
- research article
- Published by Informa UK Limited in Synthetic Communications
- Vol. 18 (12), 1331-1337
- https://doi.org/10.1080/00397918808078800
Abstract
Oxidation of N-alkylpiperidines and other cyclic, tertiary amines with Hg(ll)-EDTA complex in basic solution yields lactams, similar oxidation of N-hydroxy-plperidines gives hydroxamic acids (presumably via nitrones) and oxidation of N-unsubstituted piperidines affords lactams, probably via 1-piperideine trimers.Keywords
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