The conformations of two copper(I) complexes of 1H-benzimidazole-2(3H)-thione and thiosaccharinate
- 13 December 2011
- journal article
- Published by International Union of Crystallography (IUCr) in Acta Crystallographica Section C Crystal Structure Communications
- Vol. 68 (1), m12-m16
- https://doi.org/10.1107/s0108270111052036
Abstract
(Acetonitrile-1κN)[μ-1H-benzimidazole-2(3H)-thione-1:2κ2S:S][1H-benzimidazole-2(3H)-thione-2κS]bis(μ-1,1-dioxo-1λ6,2-benzothiazole-3-thiolato)-1:2κ2S3:N;1:2κ2S3:S3-dicopper(I)(Cu—Cu), [Cu2(C7H4NO2S2)2(C7H6N2S)2(CH3CN)] or [Cu2(tsac)2(Sbim)2(CH3CN)] [tsac is thiosaccharinate and Sbim is 1H-benzimidazole-2(3H)-thione], (I), is a new copper(I) compound that consists of a triply bridged dinuclear Cu—Cu unit. In the complex molecule, two tsac anions and one neutral Sbim ligand bind the metals. One anion bridgesviathe endocyclic N and exocyclic S atoms (μ-S:N). The other anion and one of the mercaptobenzimidazole molecules bridge the metals through their exocyclic S atoms (μ-S:S). The second Sbim ligand coordinates in a monodentate fashion (κS) to one Cu atom, while an acetonitrile molecule coordinates to the other Cu atom. The CuI—CuIdistance [2.6286 (6) Å] can be considered a strong `cuprophilic' interaction. In the case of [μ-1H-benzimidazole-2(3H)-thione-1:2κ2S:S]bis[1H-benzimidazole-2(3H)-thione]-1κS;2κS-bis(μ-1,1-dioxo-1λ6,2-benzothiazole-3-thiolato)-1:2κ2S3:N;1:2κ2S3:S3-dicopper(I)(Cu—Cu), [Cu2(C7H4NO2S2)2(C7H6N2S)3] or [Cu2(tsac)2(Sbim)3], (II), the acetonitrile molecule is substituted by an additional Sbim ligand, which binds one Cu atomviathe exocylic S atom. In this case, the CuI—CuIdistance is 2.6068 (11) Å.Keywords
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