Diels–Alder reaction of acenes with singlet and triplet oxygen – theoretical study of two-state reactivity
- 6 February 2006
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 1179-1181
- https://doi.org/10.1039/b513597d
Abstract
An interesting change in mechanism (from concerted to biradical) is described for the reaction of acenes (benzene through pentacene) with molecular oxygen (either singlet oxygen, 1Δg-O2, or triplet oxygen, 3Σ−g-O2).Keywords
This publication has 28 references indexed in Scilit:
- Organic Field-Effect Transistors from Solution-Deposited Functionalized Acenes with Mobilities as High as 1 cm2/V·sJournal of the American Chemical Society, 2005
- Pentacene Disproportionation during Sublimation for Field-Effect TransistorsJournal of the American Chemical Society, 2005
- Tetrathiafulvalenes, Oligoacenenes, and Their Buckminsterfullerene Derivatives: The Brick and Mortar of Organic ElectronicsChemical Reviews, 2004
- Effect of impurities on the mobility of single crystal pentaceneApplied Physics Letters, 2004
- Substituent Effect on Regioselectivity in Oxygenation of Multisubstituted AcenesChemistry Letters, 2004
- A computational study of the Diels–Alder reactions involving acenes: reactivity and aromaticityChemical Physics Letters, 2003
- Organic Thin Film Transistors for Large Area ElectronicsAdvanced Materials, 2002
- The Acenes: Is There a Relationship between Aromatic Stabilization and Reactivity?Organic Letters, 2001
- Diels-Alder reactivity of polycyclic aromatic hydrocarbons. 1. Acenes and benzologsJournal of the American Chemical Society, 1980
- Photoperoxidation of unsaturated organic molecules. XIV. O21.DELTA.g acceptor properties and reactivityJournal of the American Chemical Society, 1974