Quantitative Detection of OH Radicals for Investigating the Reaction Mechanism of Various Visible-Light TiO2 Photocatalysts in Aqueous Suspension
- 14 January 2013
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Physical Chemistry C
- Vol. 117 (3), 1383-1391
- https://doi.org/10.1021/jp3105166
Abstract
The reaction mechanism of visible-light responsive photocatalysts was explored by analyzing OH radicals (•OH) quantitatively by means of a coumarin fluorescence probe method. The photocatalysts investigated were various modified TiO2, i.e., nitrogen-doped, Pt-complex-deposited, Fe(III)-grafted, and Fe(III)-grafted Ru-doped TiO2. The formation rate of •OH was measured to calculate the •OH quantum yield from the absorbed intensity of 470 nm LED light. The highest quantum yield was obtained for Fe(III)-grafted Ru-doped TiO2. The •OH yield was increased on the addition of H2O2 for the Fe(III)-grafted TiO2, indicating that H2O2 is supposedly a reaction intermediate for producing •OH. The photocatalytic activity for each sample was obtained by measuring CO2 generation rate on the acetaldehyde decomposition in an aqueous suspension system and then it was compared with the •OH formation rate. Although the CO2 generation rate is positively correlated with the •OH formation rate for each photocatalyst, the values of CO2 generation were extremely larger than those of •OH. This finding indicates that the oxidation reaction takes place dominantly with surface trapped holes which probably exchange with the •OH in solution.Keywords
This publication has 43 references indexed in Scilit:
- Progress in Heterogeneous Photocatalysis: From Classical Radical Chemistry to Engineering Nanomaterials and Solar ReactorsThe Journal of Physical Chemistry Letters, 2012
- A surface science perspective on TiO2 photocatalysisSurface Science Reports, 2011
- Fundamentals and misconceptions in photocatalysisJournal of Photochemistry and Photobiology A: Chemistry, 2010
- Synthesis, Characterization, and Photocatalytic Activities of Nanoparticulate N, S-Codoped TiO2 Having Different Surface-to-Volume RatiosThe Journal of Physical Chemistry C, 2010
- TiO2 photocatalysis and related surface phenomenaSurface Science Reports, 2008
- Substrate-Specific Photocatalytic Activities of TiO2 and Multiactivity Test for Water Treatment ApplicationEnvironmental Science & Technology, 2007
- Nitrogen-doped titanium dioxide photocatalysts for visible response prepared by using organic compoundsScience and Technology of Advanced Materials, 2005
- Photoinduced reactivity of titanium dioxideProgress in Solid State Chemistry, 2004
- Visible-Light Photocatalysis in Nitrogen-Doped Titanium OxidesScience, 2001
- Environmental Applications of Semiconductor PhotocatalysisChemical Reviews, 1995