Preparation and Characterization of a Tetrabutylammonium Graphite Intercalation Compound
- 22 July 2011
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 133 (32), 12436-12438
- https://doi.org/10.1021/ja2053539
Abstract
The intercalation of tetrabutylammonium (TBA) cations into graphite by cation exchange from a sodium-ethylenediamine graphite intercalation compound yields a single-phase first-stage product, C44TBA, with a gallery expansion of 0.47 nm. The gallery dimension requires an anisotropic “flattened” cation conformation.Keywords
This publication has 35 references indexed in Scilit:
- Preparation of a Homologous Series of Graphite Alkylamine Intercalation Compounds Including an Unusual Parallel Bilayer Intercalate ArrangementChemistry of Materials, 2011
- Electrochemical preparation of graphite intercalation compounds containing a cyclic amide, [CF2(CF2SO2)2N]−Journal of Fluorine Chemistry, 2009
- Highly conducting graphene sheets and Langmuir–Blodgett filmsNature Nanotechnology, 2008
- Effects of reaction parameters on the electrochemical formation of multilayer films composed of manganese oxides and tetra-alkylammonium ionsJournal of Materials Research, 2006
- Electrochemical Synthesis of Layered Manganese Oxides Intercalated with Tetraalkylammonium IonsLangmuir, 2004
- Electric Field Effect in Atomically Thin Carbon FilmsScience, 2004
- Computational and NMR study of quaternary ammonium ion conformations in solutionPhysical Chemistry Chemical Physics, 2002
- Intercalation of Organic Ammonium Ions into Layered Graphite OxideLangmuir, 2002
- X-Ray Diffraction Study on Crystalline and Osmotic Swelling of a Layered TitanateMolecular Crystals and Liquid Crystals, 1998
- Comparison of fluoride intercalation/de-intercalation processes on graphite electrodes in aqueous and aqueous methanolic HF mediaJournal of Power Sources, 1995