Template-Assisted Growth of Nominally Cubic (100)-Oriented Three-Dimensional Crack-Free Photonic Crystals

Abstract

Three-dimensional (3D) photonic crystals (PhCs) are now beginning to acquire functionality via the use of dopants and heterostructures. However, the self-organized fabrication of large-area single crystals that are free of cracks and stacking faults has remained a challenge. We demonstrate a technology for the fabrication of (100)-oriented thin film 3D opal PhCs that exhibit no cracks over areas having no intrinsic size limit via a modified template-assisted colloidal self-assembly approach onto a patterned substrate.This technology potentially makes available large area regions of single photonic crystal, which can be used for optoelectronic devices.