The unexpected reactivity of p-tolylisocyanate towards the Keggin anion α-[PMo12O40]3–
- 1 January 1996
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 2195-2196
- https://doi.org/10.1039/cc9960002195
Abstract
In pyridine, p-tolylisocyanate reacts with [NBun 4]3[α-PMo12O40] to give a number of products, among which are the highly functionalized neutral species [Mo10(NC6H4Me-p)12(PY)2O18], the azo compound p-MeC6H4NNC6H4Me-p, and reduced derivatives of α-[PMo12O40]3–.Keywords
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