Convenient Synthesis of Alkylhydrazides by the Cobalt-Catalyzed Hydrohydrazination Reaction of Olefins and Azodicarboxylates
- 17 April 2004
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (18), 5676-5677
- https://doi.org/10.1021/ja048698u
Abstract
Treatment of olefins 2 with 1.5 equiv of di-tert-butyl azodicarboxylate (3), 1 equiv of PhSiH3, and 1.5−5 mol % of the simple Co(III) catalyst 1 in ethanol at 23 °C affords the Markovnikov hydrazide product for a broad range of olefins in 62−94% yield.Keywords
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