An Approach to Preparing Ni–P with Different Phases for Use as Supercapacitor Electrode Materials
- 19 October 2015
- journal article
- research article
- Published by Wiley in Chemistry – A European Journal
- Vol. 21 (49), 17897-17903
- https://doi.org/10.1002/chem.201502269
Abstract
Herein, we describe a simple two-step approach to prepare nickel phosphide with different phases, such as Ni2P and Ni5P4, to explain the influence of material microstructure and electrical conductivity on electrochemical performance. In this approach, we first prepared a Ni–P precursor through a ball milling process, then controlled the synthesis of either Ni2P or Ni5P4 by the annealing method. The as-prepared Ni2P and Ni5P4 are investigated as supercapacitor electrode materials for potential energy storage applications. The Ni2P exhibits a high specific capacitance of 843.25 F g−1, whereas the specific capacitance of Ni5P4 is 801.5 F g−1. Ni2P possesses better cycle stability and rate capability than Ni5P4. In addition, the Fe2O3//Ni2P supercapacitor displays a high energy density of 35.5 Wh kg−1 at a power density of 400 W kg−1 and long cycle stability with a specific capacitance retention rate of 96 % after 1000 cycles, whereas the Fe2O3//Ni5P4 supercapacitor exhibits a high energy density of 29.8 Wh kg−1 at a power density of 400 W kg−1 and a specific capacitance retention rate of 86 % after 1000 cycles.Keywords
Funding Information
- National Natural Science Foundation of China (21403099)
- Natural Science Foundation of Gansu Province (145RJZA193)
- State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology (SKLAB02014005)
This publication has 45 references indexed in Scilit:
- Tubular TiC fibre nanostructures as supercapacitor electrode materials with stable cycling life and wide-temperature performanceEnergy & Environmental Science, 2015
- A stable lithium metal interfaceNature Nanotechnology, 2014
- Inorganic nanostructured materials for high performance electrochemical supercapacitorsNanoscale, 2013
- Strongly coupled inorganic–nano-carbon hybrid materials for energy storageChemical Society Reviews, 2013
- Hierarchical NiCo2O4@MnO2core–shell heterostructured nanowire arrays on Ni foam as high-performance supercapacitor electrodesChemical Communications, 2012
- Recent Advances in Metal Oxide‐based Electrode Architecture Design for Electrochemical Energy StorageAdvanced Materials, 2012
- Co3O4/Ni(OH)2 composite mesoporous nanosheet networks as a promising electrode for supercapacitor applicationsJournal of Materials Chemistry, 2012
- A review of electrode materials for electrochemical supercapacitorsChemical Society Reviews, 2012
- Materials for electrochemical capacitorsNature Materials, 2008
- Effect of Ce4+ substitution on the structural, electrical and dielectric properties of NiAl2O4 spinelPhysica Status Solidi (a), 2005