A Dramatic Push Effect on the Homolysis of FeIII(OOR) Intermediates To Form Non‐Heme FeIVO Complexes
- 7 August 2003
- journal article
- research article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 42 (31), 3671-3673
- https://doi.org/10.1002/anie.200351694
Abstract
A pushy Lewis base: Previously unobserved non‐heme FeIVO intermediates can be trapped in the decay of FeIIIOOR species by the addition of Lewis bases (represented by the green sphere) that promote OO bond homolysis (see picture; Fe purple, O red).Keywords
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