A Phosphorescent Molecular “Butterfly” that undergoes a Photoinduced Structural Change allowing Temperature Sensing and White Emission
- 27 August 2014
- journal article
- research article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 53 (41), 10908-10912
- https://doi.org/10.1002/anie.201405293
Abstract
A butterfly-like phosphorescent platinum(II) binuclear complex can undergo a molecular structure change in which the Pt–Pt distance shortens upon photoexcitation, which leads to the formation of two distinct excited states and dual emission in the steady state, that is, greenish-blue emission from the high-energy excited state at the long Pt–Pt distance and red emission from the low-energy excited state at the short Pt–Pt distance. This photoinduced molecular structure change has a strong dependence on the molecule’s surrounding environment, allowing its application as self-referenced luminescent sensor for solid–liquid phase change, viscosity, and temperature, with greenish-blue emission in solid matrix and rising red emission in molten liquid phase. With proper control of the surrounding media to manipulate the structural change and photophysical properties, a broad white emission can be achieved from this molecular butterfly.Keywords
This publication has 75 references indexed in Scilit:
- A surface-bound molecule that undergoes optically biased Brownian rotationNature Nanotechnology, 2014
- Luminescent probes and sensors for temperatureChemical Society Reviews, 2013
- Real-Time Tracking of Phytochrome’s Orientational Changes During Pr PhotoisomerizationJournal of the American Chemical Society, 2012
- Walking moleculesChemical Society Reviews, 2011
- Light powered molecular machinesChemical Society Reviews, 2009
- Quantum dynamics of light-driven chiral molecular motorsPhysical Chemistry Chemical Physics, 2009
- Adiabatic operation of a molecular machineProceedings of the National Academy of Sciences, 2007
- Artificial Molecular Motors Powered by LightAustralian Journal of Chemistry, 2006
- Photoactive pseudorotaxanes and rotaxanes as artificial molecular machinesSynthetic Metals, 2003
- Fluorescent sensors of molecular recognition. Modified cyclodextrins capable of exhibiting guest-responsive twisted intramolecular charge transfer fluorescenceJournal of the American Chemical Society, 1993