Trialkylboron/Lanthanide Metallocene Hydride Chemistry: Polydentate Bridging of (HBEt3)- to Lanthanum
- 14 July 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 44 (16), 5820-5825
- https://doi.org/10.1021/ic0501061
Abstract
The reaction of [(C5Me5)2LaH]x with BEt3 is reported, and the solid-state structures of the lanthanum product (C5Me5)2La[(μ-H)(μ-Et)2BEt], 1, and its THF adduct (C5Me5)2La(THF)[(μ-H)(μ-Et)BEt2], 2, are compared with that of the hydride-bridged “tuckover” complex (C5Me5)2La(μ-H)(μ-η1:η5-CH2C5Me4)La(C5Me5), 3.Keywords
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