Bidirectional Chemo‐Switching of Spin State in a Microporous Framework
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- 9 June 2009
- journal article
- research article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 48 (26), 4767-4771
- https://doi.org/10.1002/anie.200806039
Abstract
The ins and outs of spin: Using the microporous coordination polymer {Fe(pz)[Pt(CN)4]} (1, pz=pyrazine), incorporating spin-crossover subunits, two-directional magnetic chemo-switching is achieved at room temperature. In situ magnetic measurements following guest vapor injection show that most guest molecules transform 1 from the low-spin (LS) state to the high-spin (HS) state, whereas CS2 uniquely causes the reverse HS-to-LS transition.Keywords
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