Novel bis-acac-O,O–Ir(iii) catalyst for anti-Markovnikov, hydroarylation of olefins operates by arene CH activation
- 13 November 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 24,p. 3000-3001
- https://doi.org/10.1039/b208680h
Abstract
A novel, thermally stable, homogeneous Ir catalyst for the anti-Markovnikov, hydroarylation of olefins is shown to operate by arene CH activation via the formation of a bis-acac-O,O phenyl–Ir(III) species.Keywords
This publication has 8 references indexed in Scilit:
- Ru-, Rh-, and Pd-Catalyzed C−C Bond Formation Involving C−H Activation and Addition on Unsaturated Substrates: Reactions and Mechanistic AspectsChemical Reviews, 2002
- Regioselective hydrophenylation of olefins catalyzed by an Ir(III) complexJournal of Molecular Catalysis A: Chemical, 2002
- Isomerization and anti-Markovnikov arylation of olefin catalyzed by an iridium complexCatalysis Letters, 2001
- Addition of C−H Bonds to the Catalytically Active Complex (PCP)Ir (PCP = η3-2,6-(tBu2PCH2)2C6H3)Journal of the American Chemical Society, 2000
- Anti-Markovnikov Olefin Arylation Catalyzed by an Iridium ComplexJournal of the American Chemical Society, 2000
- The Mechanism of Silicon−Hydrogen and Carbon−Hydrogen Bond Activation by Iridium(III): Production of a Silylene Complex and the First Direct Observation of Ir(III)/Ir(V) C−H Bond Oxidative Addition and Reductive EliminationJournal of the American Chemical Society, 2000
- Modeling the Proposed Intermediate in Alkane Carbon−Hydrogen Bond Activation by Cp*(PMe3)Ir(Me)OTf: Synthesis and Stability of Novel Organometallic Iridium(V) ComplexesOrganometallics, 1999
- .gamma.-Carbon-bonded 2,4-pentanedionato complexes of trivalent iridiumInorganic Chemistry, 1976