Remarkable Metal-Complexed Phosphorus Analogues of the Cyclopropenylcarbene–Cyclobutadiene Rearrangement
- 1 June 2011
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 133 (25), 9704-9707
- https://doi.org/10.1021/ja203083c
Abstract
In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structural changes leading to phosphorus analogues of Pettit’s seminal (η4-cyclobutadiene)iron tricarbonyl complex via multiple valence isomers along the reaction pathway and the elimination of one molecule of carbon monoxide.Keywords
This publication has 41 references indexed in Scilit:
- Organophosphorus Compounds, 118. Reactions of 1‐Chloro‐1H‐phosphirenes with NucleophilesEuropean Journal of Inorganic Chemistry, 1997
- Cooligomerization of Phosphaalkynes and Alkynes in the Coordination Sphere of Rhodium ComplexesAngewandte Chemie-International Edition, 1991
- The thermal isomerization of a silacyclobutadiene to a cyclopropenylsilylene: evidence for a stable silylene in fluid solutionJournal of the American Chemical Society, 1989
- Phosphaalkyne Cyclodimerization Using Iron ComplexesSynthesis, 1989
- First Structure Analysis and Photoelectron Spectroscopic Investigation of an Azete and an Azete‐Cobalt ComplexAngewandte Chemie-International Edition, 1988
- Silacyclobutadienes: generation of 1-mesityl-2,3,4-tri-tert-butyl-1-silacyclobutadieneJournal of the American Chemical Society, 1988
- Tri‐tert‐butylazete—The First Kinetically Stabilized AzacyclobutadieneAngewandte Chemie-International Edition, 1986
- The Cyclobutadiene ProblemAngewandte Chemie-International Edition, 1974
- A Cyclopropenylcarbene-Cyclobutadiene Rearrangement1Journal of the American Chemical Society, 1966
- Cyclobutadiene- and Benzocyclobutadiene-Iron Tricarbonyl Complexes1Journal of the American Chemical Society, 1965