Electronic Absorption Spectra of Mn2+, Fe2+, and Co2+ in Dihydrated Halide Crystals
- 1 June 1966
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 44 (11), 4159-4166
- https://doi.org/10.1063/1.1726599
Abstract
The absorption spectra of Mn2+, Fe2+, and Co2+ in dihydrated halide crystals have been studied as a function of temperature and with polarized incident radiation. The Mn2+ spectrum is quite adequately explained by considering the combined effects of a tetragonally distorted cubic potential and vibrational and/or spin—orbit perturbation on the electronic levels. The data for the Fe2+ and Co2+ crystals support the existence of potential fields of symmetry lower than tetragonal.Keywords
This publication has 22 references indexed in Scilit:
- Infrared absorption spectra of aquo complexes and the nature of co-ordination bondsSpectrochimica Acta, 1964
- Absorption Spectra and Electronic Structures of Some Tetrahedral Manganese(II) ComplexesJournal of the American Chemical Society, 1962
- The infrared absorption spectra of metal acetylacetonatesSpectrochimica Acta, 1961
- Optical Absorption Study of Co-Doped Oxide Systems. IIThe Journal of Chemical Physics, 1961
- The Optical Absorption in Manganese Zinc Fluoride Single Crystals near the N el TemperatureProceedings of the Physical Society, 1960
- Note on the gyromagnetic ratio of Co++ and on the Jahn-teller effect in Fe++Physica, 1960
- Paramagnetic Resonance and Optical Spectra of Divalent Iron in Cubic Fields. I. TheoryPhysical Review B, 1960
- Optical Absorption of CoO and MnO above and below the Néel TemperaturePhysical Review B, 1959
- Experimental and Crystal Field Study of the Absorption Spectrum at 2000 to 8000 Å. of Manganous Perchlorate in Aqueous Perchloric Acid1Journal of the American Chemical Society, 1958
- Paramagnetic and Optical Spectra of Divalent Cobalt in Cubic Crystalline FieldsPhysical Review B, 1958