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On the Nature of Li Insertion in Tin Composite Oxide Glasses
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On the Nature of Li Insertion in Tin Composite Oxide Glasses
On the Nature of Li Insertion in Tin Composite Oxide Glasses
GG
G. R. Goward
G. R. Goward
F. Leroux
F. Leroux
WP
W. P. Power
W. P. Power
GO
G. Ouvrard
G. Ouvrard
W. Dmowski
W. Dmowski
TE
T. Egami
T. Egami
L. F. Nazaraa
L. F. Nazaraa
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1 January 1999
journal article
Published by
The Electrochemical Society
in
Electrochemical and Solid-State Letters
Vol. 2
(8)
,
367-370
https://doi.org/10.1149/1.1390840
Abstract
Tin composite oxide (TCO) glass, , is a high capacity lithium storage medium that may perform as the next generation of anodes in batteries. By using X‐ray absorption spectroscopy in conjunction with lithium‐7 nuclear magnetic resonance, we have obtained a picture of the insertion and deinsertion process in TCO compared to that in , and show that these processes are more complex than was originally thought. Our results demonstrate the significance of oxygen participation in the reversible reactions at nanophase or centers, and suggest that the presence of a quasi‐flexible coordination environment in the glass may enhance the cycling properties. ©1999 The Electrochemical Society
Keywords
LITHIUM STORAGE
TCO
COORDINATION
FLEXIBLE
ABSORPTION
RESONANCE
CONJUNCTION
PICTURE
DEINSERTION
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Cited by 66 articles