TCNQ Dianion-Based Coordination Polymer Whose Open Framework Shows Charge-Transfer Type Guest Inclusion
- 1 December 2006
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (51), 16416-16417
- https://doi.org/10.1021/ja0660047
Abstract
A three-dimensional coordination framework constructed with 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) diainon has been synthesized and structurally characterized. This open framework possessing a highly electron-rich surface has an optical sensing cavity for several aromatics with crystal-to-crystal transformation and strong accommodation, which are based on a charge-transfer interaction with them.This publication has 21 references indexed in Scilit:
- A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface AreaScience, 2005
- In Situ Single-Crystal X-ray Diffraction Studies of Desorption and Sorption in a Flexible Nanoporous Molecular Framework MaterialJournal of the American Chemical Society, 2005
- A Controllable Electrochemical Fabrication of Metallic Electrodes with a Nanometer/Angstrom‐Sized Gap Using an Electric Double Layer as FeedbackAngewandte Chemie, 2005
- Crystallized Frameworks with Giant Pores: Are There Limits to the Possible?Accounts of Chemical Research, 2005
- Design, Chirality, and Flexibility in Nanoporous Molecule-Based MaterialsAccounts of Chemical Research, 2005
- Crystal-to-Crystal Guest Exchange of Large Organic Molecules within a 3D Coordination NetworkJournal of the American Chemical Society, 2004
- Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four [fac-Re(CO)3(bpy)]+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB)Inorganic Chemistry, 2003
- An Investigation of the Factors that Influence the Decomposition of 7,7‘,8,8‘-Tetracyanoquinodimethane (TCNQ) and Its Salts to, and Structural Characterization of, the α,α-Dicyano-p-toluoylcyanide AnionChemistry of Materials, 2000
- Incorporation of MnIII and FeII Complexes into TCNQ Networks: Preparations, Crystal Structures, and Magnetic Properties of [MnIII(salen)(TCNQ)0.5][MnIII(salen)(TCNQ)0.5(CH3OH)]CH3OH·H2O and [FeII(CH3OH)4(TCNQ)2]TCNQ·2CH3CNBulletin of the Chemical Society of Japan, 1995
- Front coverJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1985