Geometrical Structure of the Gold–Iron(III) Oxide Interfacial Perimeter for CO Oxidation

Abstract

The geometrical structure of the Au‐Fe₂O₃ interfacial perimeter, which is generally considered as the active sites for low‐temperature oxidation of CO, was examined. It was found that the activity of the Au/Fe₂O₃ catalysts not only depends on the number of the gold atoms at the interfacial perimeter but also strongly depends on the geometrical structure of these gold atoms, which is determined by the size of the gold particle. Aberration‐corrected scanning transmission electron microscopy images unambiguously suggested that the gold particles, transformed from a two‐dimensional flat shape to a well‐faceted truncated octahedron when the size slightly enlarged from 2.2 to 3.5 nm. Such a size‐induced shape evolution altered the chemical bonding environments of the gold atoms at the interfacial perimeters and consequently their catalytic activity. For Au particles with a mean size of 2.2 nm, the interfacial perimeter gold atoms possessed a higher degree of unsaturated coordination environment while for Au particles with a mean size of 3.5 nm the perimeter gold atoms mainly followed the atomic arrangements of Au {111} and {100} facets. Kinetic study, with respect to the reaction rate and the turnover frequency on the interfacial perimeter gold atom, found that the low‐coordinated perimeter gold atoms were intrinsically more active for CO oxidation. ¹⁸O isotopic titration and Infrared spectroscopy experiments verified that CO oxidation at room temperature occurred at the Au‐Fe₂O₃ interfacial perimeter, involving the participation of the lattice oxygen of Fe₂O₃ for activating O₂ and the gold atoms for CO adsorption and activation.