Hydrogen Clathrate Structures in Rare Earth Hydrides at High Pressures: Possible Route to Room-Temperature Superconductivity
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- 8 September 2017
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 119 (10), 107001
- https://doi.org/10.1103/physrevlett.119.107001
Abstract
Room-temperature superconductivity has been a long-held dream and an area of intensive research. Recent experimental findings of superconductivity at 200 K in highly compressed hydrogen (H) sulfides have demonstrated the potential for achieving room-temperature superconductivity in compressed H-rich materials. We report first-principles structure searches for stable H-rich clathrate structures in rare earth hydrides at high pressures. The peculiarity of these structures lies in the emergence of unusual H cages with stoichiometries , , and , in which H atoms are weakly covalently bonded to one another, with rare earth atoms occupying the centers of the cages. We have found that high-temperature superconductivity is closely associated with H clathrate structures, with large H-derived electronic densities of states at the Fermi level and strong electron-phonon coupling related to the stretching and rocking motions of H atoms within the cages. Strikingly, a yttrium (Y) clathrate structure of stoichiometry is predicted to be a potential room-temperature superconductor with an estimated of up to 303 K at 400 GPa, as derived by direct solution of the Eliashberg equation.
Keywords
Funding Information
- National Natural Science Foundation of China (11534003)
- China Postdoctoral Science Foundation (2016M590033)
- Natural Science Foundation of Henan Province (162300410199)
- Henan University (17HASTIT015)
- Jilin University (201602)
- Engineering and Physical Sciences Research Council (EP/J017639/1)
- Royal Society
- University of Cambridge (EP/P022596/1)
- Science Challenge Project (TZ2016001)
- National Key Research and Development Program of China (2016YFB0201200)
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