Paramagnetic Resonance and Relaxation of Trivalent Rare-Earth Ions in Calcium Fluoride. II. Spin-Lattice Relaxation
- 15 June 1964
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 134 (6A), A1504-A1516
- https://doi.org/10.1103/physrev.134.a1504
Abstract
The temperature dependence of the spin-lattice relaxation time of trivalent rare-earth impurities in Ca has been measured at 9.6 kMc/sec using pulse saturation techniques. The rare earths investigated include Kramers ions (, , , , ), one non-Kramers ion (), and one -state ion (). The relaxation of ions in lattice sites of cubic, tetragonal, and trigonal crystal-field symmetries have been studied and are found to be different. At liquid-helium temperatures the relaxation usually exhibits a temperature dependence; however, the magnitudes are approximately two orders-of-magnitude shorter than estimated single-phonon relaxation times based upon the orbit-lattice interaction. Measurements of the relaxation in five samples containing from 0.08 to 1.6% Ce combined with results from other ions show that decreases with increasing rare-earth concentration. Multiple exponential recoveries from saturation are observed at low temperatures and are discussed with respect to possible cross-relaxation within inhomogeneous spin systems and to other faster relaxing systems. At higher temperatures examples of both Raman and Orbach two-phonon relaxation processes are found. Calculations of two-phonon relaxation times using estimated values of the dynamic crystal fields, energy level structures, and ion wave functions yield coarse order-of-magnitude agreement with experimental values.
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