ON THIOSEMICARBAZONE–COPPER (I) COMPLEXES. PART IV
- 1 January 1964
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 42 (1), 17-19
- https://doi.org/10.1139/v64-003
Abstract
The structure of thiosemicarbazone–copper (I) complexes has been studied further and new data have been obtained. The most probable structure has the metal linearly coordinated to a sulphur atom of a thiosemicarbazone molecule and a nitrogen atom of a second molecule. The diamagnetism of the complexes can be accounted for by a copper–copper interaction. Molecular weights of two typical complexes have been measured by a vapor pressure lowering method in benzene. The complexes were found to associate in this solvent but appeared as dimers at infinite dilution.Keywords
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