Stepwise Guest Adsorption with Large Hysteresis in a Coordination Polymer {[Cu(bhnq)(THF)2](THF)}n Constructed from a Flexible Hingelike Ligand
- 25 April 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 45 (11), 4322-4324
- https://doi.org/10.1021/ic060046e
Abstract
Reversible vapochromic behavior of a porous copper(II) coordination polymer {[Cu(bhnq)(THF)2](THF)}n (1; THF = tetrahydrofuran) constructed from a flexible hingelike ligand H2bhnq [2,2'-bis(3-hydroxy-1,4-naphthoquinone)] has been investigated by adsorption measurements. The isotherms show large hysteretic and stepwise profiles, suggesting the occurrence of the guest-induced framework transformation. The dynamic coil-like behavior of 1 can be controlled through the change of the hydrogen-bonding interactions caused by the reversible and selective incorporation of guest molecules.Keywords
This publication has 18 references indexed in Scilit:
- Highly controlled acetylene accommodation in a metal–organic microporous materialNature, 2005
- Direct Characterization of Enzyme–Substrate Complexes by Using Electrosonic Spray Ionization Mass SpectrometryAngewandte Chemie-International Edition, 2005
- Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of FrameworksAccounts of Chemical Research, 2005
- Dynamic porous properties of coordination polymers inspired by hydrogen bondsChemical Society Reviews, 2005
- Single‐Crystal Adsorbents: A New Observation Field for Light AggregatesAngewandte Chemie-International Edition, 2004
- The Hydrothermal Synthesis of Zeolites: History and Development from the Earliest Days to the Present TimeChemical Reviews, 2003
- Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic SolidScience, 2002
- Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane StorageScience, 2002
- A homochiral metal–organic porous material for enantioselective separation and catalysisNature, 2000
- From Microporous to Mesoporous Molecular Sieve Materials and Their Use in CatalysisChemical Reviews, 1997