The oxygen isotopic composition of the oceans, sediments and the seafloor
- 1 April 1998
- journal article
- Published by Elsevier BV in Chemical Geology
- Vol. 145 (3-4), 263-273
- https://doi.org/10.1016/s0009-2541(97)00147-2
Abstract
The oxygen isotope history of seawater remains controversial despite decades of study. Isotopic data from fossils and chemical sediments generally indicate significantly 18O-depleted seas during the Paleozoic and earlier, whereas the isotopic composition of contemporaneous ophiolites imply an ocean indistinguishable from today's. Uncertainty in δ18O of seawater limits the usefulness of oxygen isotope geothermometry as well as challenges current paradigms of plate tectonics. This paper reviews the controversy and revises earlier estimates on the 18O-balance within the hydrosphere. The conclusion is that the δ18O of seawater is mainly buffered by hydrothermal and weathering processes at mid-ocean ridges to a δ18O value of about 0‰ (SMOW). At values other than 0±2‰, a large countervailing flux of 18O would return seawater to near 0‰. The δ18O of Paleozoic, Proterozoic and Archean ophiolites support the above model. The discrepancy in δ18O between most (but not all) post-Mississippian fossils and chemical sediments and ophiolites must be explained as a combination of: (1) loss of integrity of δ18O in sediments and fossils; (2) warmer paleoenvironments that lead to the precipitation of lower δ18O exogenic products; (3) isotopically distinct water masses in inland seas that host the fossils but which are not well mixed with the open ocean that alters the seafloor.Keywords
This publication has 51 references indexed in Scilit:
- Nature and composition of the continental crust: A lower crustal perspectiveReviews of Geophysics, 1995
- Very high 18o enrichment in Archean cherts from South India: implications for Archean ocean temperatureTerra Nova, 1994
- Earth's earliest continental lithosphere, hydrothermal flux and crustal recyclingLithos, 1993
- The temperatures and oxygen-isotope composition of early Devonian oceansNature, 1993
- Oxygen isotopic homogeneity of the Earth: new evidenceEarth and Planetary Science Letters, 1992
- No water, no granites ‐ No oceans, no continentsGeophysical Research Letters, 1983
- Oxygen-isotope geochemistry of Archean granitoid gneisses and related rocks in the English River Subprovince, northwestern OntarioPrecambrian Research, 1983
- Oxygen isotope geochemistry of cherts from the Onverwacht Group (3.4 billion years), Transvaal, South Africa, with implications for secular variations in the isotopic composition of chertsEarth and Planetary Science Letters, 1978
- Hydrogen and oxygen isotope evidence for sea-water-hydrothermal alteration and ore deposition, Troodos complex, CyprusGeological Society, London, Special Publications, 1977
- Oxygen Isotope Geochemistry of Submarine GreenstonesCanadian Journal of Earth Sciences, 1972