Stereoselective Synthesis, Efficient Light Emission, and High Bipolar Charge Mobility of Chiasmatic Luminogens

Abstract
Stereoregular tetraphenylethene derivatives (Z)‐o‐BCaPTPE and (Z)‐o‐BTPATPE featured with chiasmatic conformations and aggregation‐enhanced emission characteristics are synthesized using a McMurry reaction. Both luminogens exhibit high hole and electron mobilities. Organic light‐emitting diodes (OLEDs) using (Z)‐o‐BCaPTPE and (Z)‐o‐BTPATPE as both the light‐emitting and electron‐transporting layers show high efficiencies.