Metal Supported on Dendronized Magnetic Nanoparticles: Highly Selective Hydroformylation Catalysts
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- 22 March 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (15), 5279-5282
- https://doi.org/10.1021/ja060140u
Abstract
A method for homogenizing heterogeneous catalyst is described. The method is based on growing polyaminoamido (PAMAM) dendrons on silica-coated magnetic nanoparticles. After the dendronizing process, the silica-coated magnetic nanoparticles are more stable and more soluble in organic solvents. The dendronized particles are phosphonated, complexed with [Rh(COD)Cl]2, and applied in catalytic hydroformylation reactions. These new catalysts are proven to be highly selective and reactive.Peer reviewed: YesNRC publication: YeKeywords
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