A Convenient Method for the Preparation of Inverted tert-Alkyl Carboxylates from Chiral tert-Alcohols by a New Type of Oxidation−Reduction Condensation Using 2,6-Dimethyl-1,4-benzoquinone
- 9 August 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (35), 10538-10539
- https://doi.org/10.1021/ja0303844
Abstract
Oxidation−reduction condensation using in situ-formed alkoxydiphenylphosphines, 2,6-dimethyl-1,4-benzoquinone, and carboxylic acids provided a new and efficient method for the preparation of inverted tert-alkyl carboxylates from various chiral tertiary alcohols.Keywords
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