Electrical and dielectric properties of polyaniline–Al2O3 nanocomposites derived from various Al2O3 nanostructures
- 31 January 2011
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 21 (11), 3952-3959
- https://doi.org/10.1039/c0jm03908j
Abstract
Four Al2O3 nanostructures (i.e. nanofiber, nanoplatelet, nanorod and nanoflake) have been successfully synthesized via hydrothermal procedures followed by a dehydration process. Subsequently, polyaniline (PANI) nanocomposites incorporating these four Al2O3 nanostructures have been fabricated using a surface initialized polymerization (SIP) method. Both TEM and SEM are used to characterize the morphologies of the Al2O3 nanostructures and PANI/Al2O3 nanocomposites. X-Ray diffraction results reveal that the morphology of the nanofiller has a significant effect on the crystallization behavior of the PANI during polymerization. The electrical conductivity and dielectric permittivity of these nanocomposites are strongly related to both the morphology of the filler and the dispersion quality. Temperature-dependent-conductivity measurements from 50–290 K show that the electron transportation of the nanocomposites follows a quasi 3-d variable range hopping (VRH) conduction mechanism. The extent of charge carrier delocalization calculated from VRH is well correlated to the dielectric response of these nanocomposites. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) results reveal an enhanced thermal stability of the PANI/Al2O3 nanocomposites as compared to that of pure PANI due to the strong interaction between the nanofillers and polymer matrix. The mechanism of the SIP method is also elaborated in this work.Keywords
This publication has 51 references indexed in Scilit:
- Polyaniline-tungsten oxide metacomposites with tunable electronic propertiesJournal of Materials Chemistry, 2010
- Electrical properties of polyaniline doped with metal ionsJournal of Physics D: Applied Physics, 2009
- Synthesis and characterization of chromium doped boehmite nanofibresThermochimica Acta, 2009
- Synthesis of platelet-shaped boehmite and γ-alumina nanoparticles via an aqueous routeCeramics International, 2008
- Crystallization and orientation studies in polypropylene/single wall carbon nanotube compositePolymer, 2003
- Enhancement of Room Temperature Electrical Conductivity of Polypyrrole by Chemical ModificationThe Journal of Physical Chemistry B, 2002
- Synthesis and electrochromic properties of mesoporous tungsten oxideJournal of Materials Chemistry, 2000
- Hydrothermal preparation and characterization of boehmitesMaterials Letters, 2000
- Optimization of the Textural Characteristics of an Alumina To Capture Contaminants in Natural GasLangmuir, 1996
- X-ray structure of polyanilineMacromolecules, 1991