Use of Native and Chemically Modified Cyclodextrins for the Capillary Electrophoretic Separation of Enantiomers
- 1 April 1992
- journal article
- research article
- Published by Informa UK Limited in Journal of Liquid Chromatography
- Vol. 15 (6-7), 1023-1040
- https://doi.org/10.1080/10826079208018848
Abstract
Capillary zone electrophoresis is shown to be useful for the separation of select enantiomers via the use of mobile phases containing cyclodextrins (CDs). Both native and chemically modified CDs are utilized herein. Parameters important in achieving enantiomeric separations are CD type, concentration, and mobile phase pH. In addition, rapid (1 minute) enantiomeric separations are demonstrated. Experimental parameters important in attaining short analysis times are discussed.Keywords
This publication has 17 references indexed in Scilit:
- Use of cyclodextrins in capillary zone electrophoresis : Resolution of terbutaline and propranolol enantiomersJournal of Chromatography A, 1991
- Determination of metal ions by capillary zone electrophoresis with on-column chelation using 8-hydroxyquinoline-5-sulfonic acidAnalytical Chemistry, 1991
- Resolution of optical isomers by capillary zone electrophoresis: Study of enantiomeric and diastereoisomeric Co(III) complexes with ethylenediamine and amino acid ligandsJournal of Microcolumn Separations, 1989
- Capillary zone electrophoresis-mass spectrometry using an electrospray ionization interfaceAnalytical Chemistry, 1988
- Miniaturisation in pressure and electroendosmotically driven liquid chromatography: Some theoretical considerationsChromatographia, 1987
- Effect of addition of organic solvent on the separation of positional isomers in high-voltage capillary zone electrophoresisAnalytical Chemistry, 1987
- Electrokinetic resolution of amino acid enantiomers with copper(II)-aspartame support electrolyteAnalytical Chemistry, 1987
- Capillary zone electrophoresis of proteins in untreated fused silica tubingAnalytical Chemistry, 1986
- Electrokinetic chromatography with 2-O-carboxymethyl-β-cyclodextrin as a moving “stationary” phaseJournal of Chromatography A, 1985
- Zone electrophoresis in open-tubular glass capillariesAnalytical Chemistry, 1981