Thermally Stable Donor–Acceptor Type (Alkynyl)Gold(III) TADF Emitters Achieved EQEs and Luminance of up to 23.4% and 70 300 cd m−2 in Vacuum‐Deposited OLEDs

Abstract

Thermally stable, strongly luminescent gold-TADF emitters are the clue to realize practical applications of gold metal in next generation display and lighting technology, a scarce example of which is herein described. A series of donor–acceptor type cyclometalated gold(III) alkynyl complexes with some of them displaying highly efficient thermally activated delayed fluorescence (TADF) with Φ up to 88% in thin films and emission lifetimes of ≈1–2 µs at room temperature are developed. The emission color of these complexes is readily tunable from green to red by varying the donor unit and cyclometalating ligand. Vacuum-deposited organic light-emitting diodes (OLEDs) with these complexes as emissive dopants achieve external quantum efficiencies (EQEs) and luminance of up to 23.4% and 70 300 cd m⁻², respectively.