Retrograde diagenesis, a widespread process on a regional scale
- 1 March 2005
- journal article
- Published by Mineralogical Society in Clay Minerals
- Vol. 40 (1), 93-104
- https://doi.org/10.1180/0009855054010158
Abstract
Pelitic and basic rocks occurring within prograde sequences in Portugal, Spain and Hungary have been studied by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The minerals formed in typical prograde reactions define the general sequences, but smectite, chlorite-smectite (corrensite) and/or berthierine were found to have replaced chlorite, whereas kaolinite and mixed-layer illite-smectite replaced illite-muscovite. Alteration occurred under conditions normally associated with diagenesis, subsequent to regional metamorphism, and we therefore refer to such processes with the term “retrograde diagenesis”. In the cases studied and in other cited examples, reactions occurred on a regional basis via pervasive fluids under open-system conditions inferred to be related to tectonic stress. The observed alterations could generally not be inferred from XRD data, although the presence of pure smectite in sediments other than bentonite is suggestive of retrograde relations, especially where other minerals are consistent with a higher grade of diagenesis. Retrograde diagenesis is readily observed through imaging of textures by TEM, however. Textural features show that retrograde reactions are more common than generally assumed, and that care should be used in interpreting geological events where appropriate textural relations are not seen.Keywords
This publication has 22 references indexed in Scilit:
- First-principles study of illite–smectite and implications for clay mineral systemsNature, 2002
- Comparison of Evolution of Trioctahedral Chlorite/Berthierine/Smectite in Coeval Metabasites and Metapelites from Diagenetic to Epizonal GradesClays and Clay Minerals, 2001
- Comparison of diagenetic and low-grade metamorphic evolution of chlorite in associated metapelites and metabasites: an integrated TEM and XRD studyJournal of Metamorphic Geology, 2000
- Transmission Electron Microscopy Study of Illitization in Pelites from the Iberian Range, Spain: Layer-by-Layer Replacement?Clays and Clay Minerals, 2000
- Associations between burial diagenesis of smectite, chemical remagnetization, and magnetite authigenesis in the Vocontian trough, SE FranceJournal of Geophysical Research, 2000
- Diagenesis-very low-grade metamorphism of clastic Cambrian and Ordovician sedimentary rocks in the Iberian Range (Spain)Clay Minerals, 1998
- Evolution of Illite/Smectite from Early Diagenesis Through Incipient Metamorphism in Sediments of the Basque-Cantabrian BasinClays and Clay Minerals, 1996
- Transmission and Analytical Electron Microscopic Study of Mixed-Layer Illite/Smectite Formed as an Apparent Replacement Product of Diagenetic Illite1Clays and Clay Minerals, 1990
- Transmission Electron Microscopic Study of Coexisting Pyrophyllite and Muscovite: Direct Evidence for the Metastability of Illite1Clays and Clay Minerals, 1990
- Fluids expelled tectonically from orogenic belts: Their role in hydrocarbon migration and other geologic phenomenaGeology, 1986