Depressed Phase Transition in Solution-Grown VO2 Nanostructures

Abstract

The first-order metal—insulator phase transition in VO₂ is characterized by an ultrafast several-orders-of-magnitude change in electrical conductivity and optical transmittance, which makes this material an attractive candidate for the fabrication of optical limiting elements, thermochromic coatings, and Mott field-effect transistors. Here, we demonstrate that the phase-transition temperature and hysteresis can be tuned by scaling VO₂ to nanoscale dimensions. A simple hydrothermal protocol yields anisotropic free-standing single-crystalline VO₂ nanostructures with a phase-transition temperature depressed to as low as 32 °C from 67 °C in the bulk. The observations here point to the importance of carefully controlling the stochiometry and dimensions of VO₂ nanostructures to tune the phase transition in this system.