Rate acceleration of the intramolecular diels-alder reaction with furan-diene by anchoring substitution : The t-butyl effect revisited.
- 12 March 1993
- journal article
- Published by Elsevier BV in Tetrahedron Letters
- Vol. 34 (11), 1831-1832
- https://doi.org/10.1016/s0040-4039(00)60791-8
Abstract
No abstract availableKeywords
This publication has 11 references indexed in Scilit:
- gem-Dialkyl effect in the intramolecular Diels-Alder reaction of 2-furfuryl methyl fumarates: the reactive rotamer effect, the enthalpic basis for acceleration, and evidence for a polar transition stateJournal of the American Chemical Society, 1991
- Synthetic and kinetic studies of the intramolecular Diels-Alder reactions of cycloalkenylallenylphosphine oxidesThe Journal of Organic Chemistry, 1990
- Factors affecting ease of ring formation. The effect of anchoring substitution on the rate of an intramolecular diels-alder reaction with furan-dieneTetrahedron Letters, 1988
- Intramolecular Diels-Alder reactions with furan: The gem-dialkyl effect revisitedTetrahedron Letters, 1985
- Stereopopulation control. 9. Rate and equilibrium enhancement in the lactonization of (o-hydroxyphenyl)acetic acidsThe Journal of Organic Chemistry, 1983
- Stereochemical control in the intramolecular Diels-Alder reaction. 2. Structural and electronic effects on reactivity and selectivityJournal of the American Chemical Society, 1982
- Effective Molarities for Intramolecular ReactionsPublished by Elsevier BV ,1980
- The energetics of neighbouring group participationChemical Society Reviews, 1973
- The Effect of Geminal Substitution Ring Size and Rotamer Distribution on the Intramolecular Nucleophilic Catalysis of the Hydrolysis of Monophenyl Esters of Dibasic Acids and the Solvolysis of the Intermediate AnhydridesJournal of the American Chemical Society, 1960
- XL.—The conditions underlying the formation of unsaturated and of cyclic compounds from halogenated open-chain derivatives. Part I. Products derived from α-halogenated glutaric acidsJournal of the Chemical Society, Transactions, 1921