Between red and yellow: evidence of intermediates in a vapochromic Pt(ii) salt
- 15 August 2013
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 49 (80), 9161-9163
- https://doi.org/10.1039/c3cc45418e
Abstract
[Pt(tpy)Cl]ClO4·H2O (1·H2O) changes from red to yellow upon dehydration due to increased PtPt distances. Spectroscopic, diffraction, gravimetric and calorimetric data demonstrate the presence of intermediates during hydration and dehydration which signifies surprising mechanistic complexity in the vapochromic response.Keywords
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