(η5-Cyclopentadienyl)(η4-di- and tetra-phosphorylcyclobutadiene)cobalt(i): Synthesis, structure, and formation of 1-D coordination polymer
- 25 July 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 17,p. 1876-1877
- https://doi.org/10.1039/b204779a
Abstract
(η5-Cyclopentadienyl)(η4-di- and tetra-phosphorylcyclobutadiene)cobalt(I) complexes were synthesized by the reaction of mono- and diphosphorylacetylenes with CpCo(CO)2, respectively. The tetraphosphoryl derivative has proved to work as a bis-bidentate ligand affording a one-dimensional coordination polymer with Ce(III).Keywords
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