Atomic-Scale Chemistry of Metal Surfaces
- 1 March 1993
- journal article
- Published by IOP Publishing in Japanese Journal of Applied Physics
- Vol. 32 (3S)
- https://doi.org/10.1143/jjap.32.1389
Abstract
The idea of pseudo-molecules is deduced from reviewing the results of scanning tunneling microscopy (STM) of metal surfaces. Ni(110), Cu(110), and Ag(110) surfaces exposed to H2 or O2 at room temperature reveal the formation of one-dimensional pseudo-molecules, which is essentially different from the phenomenon of adsorption. The pseudo-molecules produced on the surface are in an ordered arrangement on these metal surfaces, where the arrangement is influenced by their lateral interaction. The -Cu-O- chains oriented along the direction coalesce to form a p(2×1) arrangement on the Cu(110), but the added -Ag-O- rows on the Ag(110) surface may not prefer the p(2×1) structure, because the p(2×1) -Ag-O- added row induces a large distortion of the substrate Ag atoms. As a result, the added -Ag-O- rows undergo sequential change of the p(n×1) structures. When the p(2×1) -Cu-O- island is annealed at 550-640 K, the p(2×1) overlayer bunches into regular-sized in-phase p(2×1) -Cu-O- islands. In contrast, reordering of the (2×1) -Ag-O- overlayer to (4×1) at 500 K yields narrow out-of-phase (4×1) domains with the wavering domain boundaries. Based on these results, the influence of pseudomolecules on catalysis is predicted.Keywords
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