Switching of two amine ligands via an SN2-type mechanism in a coordinated form of 2,6-bis(N,N-dimethylaminomethyl)phenylboronates
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 2499-2500
- https://doi.org/10.1039/c39950002499
Abstract
Facile exchange between the intramoleculariy coordinated and uncoordinated amine ligands in the title compounds is evidenced by NMR spectroscopy in solution, whereas the dynamic process is frozen in the solid phase as shown by X-ray crystallography.Keywords
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