TOF-2: A Large 1D Channel Thorium Organic Framework
- 1 March 2008
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 130 (12), 3762-3763
- https://doi.org/10.1021/ja800395q
Abstract
A new neutral 1D channel thorium organic framework material (TOF-2) has been synthesized under hydrothermal conditions. TOF-2 exhibits a hexagonal channel structure consisting of eight-coordinate ThO6F2 polyhedra and 1,3,5-benzentricarboxylate ligands. The channels run along the c-axis and are approximately 13 Å in diameter. The single-crystal X-ray structure suggests that the amount of void space is 41%. The structure is stable to ca. 400 °C. Gas adsorption measurements show deferential gas uptake behavior.This publication has 29 references indexed in Scilit:
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