High frequency EPR investigations of gadolinium(III)-doped strontium aluminates

Abstract

The high frequency EPR spectra of SrAl₂O₄ doped with gadolinium(III) as a probe are discussed, focusing on the sites occupied by the lanthanides. This is because the emission due to europium(II) of SrAl₂O₄:Eu,Ln (Ln: lanthanides) is significantly affected by such substitution. The EPR spectrum of SrAl₂O₄:Dy,Gd showed a pattern typical for two overlapping resonances of ⁸S_7/2 state ions with a λ = ∣D/E∣ of ⅓, suggesting that the gadolinium(III) sites have very low symmetry. From a comparison of the experimental and simulated EPR spectra it was found that both gadolinium(III) and europium(II) ions occupy strontium sites.