Monte Carlo simulation of the complete set of molten alkali halides
- 10 February 1986
- journal article
- Published by IOP Publishing in Journal of Physics C: Solid State Physics
- Vol. 19 (4), 453-465
- https://doi.org/10.1088/0022-3719/19/4/008
Abstract
The results of Monte Carlo simulations of the complete family of molten alkali halides with a consistent set of inter-ionic potentials are reported. It is found that the structures of the melts with a common cation are isomorphous, the density scaling approximately with the sum of the ionic radii. Within groups with a common anion the local coordination varies from tetrahedral for Li+ salts to octahedral for Cs+ salts. General agreement is found with the available experimental results and with the results of other simulations using different potentials.Keywords
This publication has 48 references indexed in Scilit:
- Molecular dynamics studies of molten NaIPhilosophical Magazine Part B, 1983
- Comments on the structure of molten saltsJournal of Physics C: Solid State Physics, 1982
- Collective dynamical properties of molten salts: molecular dynamics calculations on sodium chlorideProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1977
- Density fluctuations in molten salts. II. Molecular dynamics study of liquid RbBrPhysical Review A, 1976
- The structure of molten NaCl from a simulation model which allows for the polarization of both ionsJournal of Physics C: Solid State Physics, 1976
- Transport properties of molten alkali halidesPhysical Review A, 1976
- Monte Carlo and HNC calculations for molten potassium chlorideJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1976
- Simulation of molten NaI including polarization effectsJournal of Physics C: Solid State Physics, 1975
- Rigid-ion models of the interionic potential in the alkali halidesJournal of Physics C: Solid State Physics, 1974
- Light Scattering from Ionic LiquidsThe Journal of Chemical Physics, 1972