Neutron-Scattering Study of the Structural Phase Transition in the One-Dimensional Conductor K2Pt(CN)4Br0.3·3D2O

Abstract
We report a study of the temperature dependence of the 2kF instability in the one-dimensional conductor K2Pt(CN)4 Br0.30 ·3D2O using a neutron scattering technique. Whereas the extra scattering at room temperature has a one-dimensional character corresponding to a periodicity along the C axis of 6.66 Pt-Pt spacings, below 220 K it indicates the development of a three-dimensional superlattice structure with a new unit cell 2a×2a×6.66c. However, this transition seems to be incomplete, in the sense that the coupling between adjacent chains does not achieve long-range order.