Nanoscale Homochiral C3-Symmetric Mixed-Valence Manganese Cluster Complexes with Both Ferromagnetic and Ferroelectric Properties
- 10 March 2010
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 132 (12), 4044-4045
- https://doi.org/10.1021/ja910310p
Abstract
Both ferromagnetic and ferroelectric properties were observed in two enantiomerically pure nanoscale manganese cluster complexes supported by chiral Schiff base ligands, each of which comprises a 22-nucleus mixed-valence manganese(II/III) supratetrahedral cluster cation and an equilateral-triangle trinuclear manganese(III) cluster anion with C3 symmetry.Keywords
This publication has 37 references indexed in Scilit:
- A {Co32} Nanosphere Supported by p-tert-Butylthiacalix[4]areneJournal of the American Chemical Society, 2009
- A 64-Nuclear Cubic Cage Incorporating Propeller-like FeIII8 Apices and HCOO− EdgesJournal of the American Chemical Society, 2008
- Molecular spintronics using single-molecule magnetsNature Materials, 2008
- Trading Templates: Supramolecular Transformations between {CoII13} and {CoII12} NanoclustersJournal of the American Chemical Society, 2007
- Giant Heterometallic Cu17Mn28 Cluster with Td Symmetry and High-Spin Ground StateJournal of the American Chemical Society, 2007
- Diels-Alder in Aqueous Molecular Hosts: Unusual Regioselectivity and Efficient CatalysisScience, 2006
- Single-Molecule Magnets: A Mn25 Complex with a Record S = 51/2 Spin for a Molecular SpeciesJournal of the American Chemical Society, 2004
- Quantum computing in molecular magnetsNature, 2001
- Single-Molecule MagnetsMRS Bulletin, 2000
- Structural and Functional Aspects of Metal Sites in BiologyChemical Reviews, 1996