Na2S–Carbon Nanotube Fabric Electrodes for Room‐Temperature Sodium–Sulfur Batteries
- 29 January 2015
- journal article
- research article
- Published by Wiley in Chemistry – A European Journal
- Vol. 21 (11), 4233-4237
- https://doi.org/10.1002/chem.201405344
Abstract
A unique sodium sulfide (Na2S) cathode is developed, which will allow the use of sodium-free anodes for room-temperature sodium–sulfur (Na–S) batteries. To overcome the “inert” nature of the Na2S, a special cathode structure is developed by spreading the multi-walled carbon nanotube (MWCNT)-wrapped Na2S particles onto MWCNT fabrics. Spectroscopic and electrochemical analyses reveal a series of polysulfide intermediates involved in the charge/discharge of the cell. The Na–S battery prepared in full discharge state with the Na2S/MWCNT cathode provides a remarkable capacity of 500 A h kg−1 (based on sulfur mass) after 50 cycles.This publication has 40 references indexed in Scilit:
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