Fractal Structures Formed by Kinetic Aggregation of Aqueous Gold Colloids

Abstract
We use transmission-electron micrographs to study the structure formed by the irreversible kinetic aggregation of uniformly sized aqueous gold colloids. The structures are highly ramified and exhibit a scale invariance that is well described as a fractal with a Hausdorff dimension of ∼ 1.75. This value is in excellent agreement with recent computer simulations of diffusion-limited aggregation when the clusters themselves are allowed to aggregate.