Load Distribution in Native Cellulose

Abstract

The properties of cellulose materials are dependent on interactions between and within the cellulose chains. To investigate the deformation behavior of cellulose and its relation to molecular straining, sheets with fibers oriented preferably in one direction were studied by dynamic FT-IR spectroscopy. Celluloses with different origins (spruce pulp, Cladophora cellulose, cotton linters) were used. The sheets were stretched sinusoidally at low strains and small amplitudes while being irradiated with polarized infrared radiation. The cellulose fibers showed mainly an elastic response. The cellulose fibers showed mainly an elastic response. The glucose rings and the C−O−C bridges connecting adjacent rings, as well as the O(3)H···O(5) intramolecular hydrogen bonds are the components mainly deformed under stress, whereas the O(2)H···O(6) intramolecular hydrogen bonds play a minor role. The load distribution was also found to be different in the different allomorphic forms of cellulose I, namely, I_α and I_β.