Syntheses, structures and magnetic properties of macrocyclic Schiff base-supported homodinuclear lanthanide complexes
- 31 July 2018
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 47 (33), 11696-11704
- https://doi.org/10.1039/c8dt02243g
Abstract
Five new homodinuclear lanthanide complexes with the general formula [(acac)4Ln2(L)] (Ln3+ = Dy3+ (1), Tb3+ (2), Ho3+ (3), Er3+ (4), and Gd (5)) were synthesized by one-pot [2 + 2] condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane in the presence of various lanthanide acetylacetonates. The eight-coordinate Ln(III) centre adopts a slightly distorted square antiprism geometry with D4d symmetry. Theoretical analysis and magnetic measurements reveal that the corresponding Dy complex 1 exhibits slow magnetic relaxation behavior, characteristic of a typical SMM with the intramolecular ferromagnetic Dy3+⋯Dy3+ interaction.Keywords
Funding Information
- National Natural Science Foundation of China (21401085, 21501195, 11774178)
This publication has 93 references indexed in Scilit:
- Slow relaxation processes of salen type Dy2 complex and 1D ionic spiral Dyn coordination polymerCrystEngComm, 2012
- Series of Lanthanide Organometallic Single-Ion MagnetsInorganic Chemistry, 2012
- Molecular spins for quantum information technologiesChemical Society Reviews, 2011
- A Caveat for Single-Molecule Magnetism: Non-linear Arrhenius PlotsChemphyschem, 2009
- Structure, Magnetism, and Theoretical Study of a Mixed-Valence CoII3CoIII4 Heptanuclear Wheel: Lack of SMM Behavior despite Negative Magnetic AnisotropyJournal of the American Chemical Society, 2008
- Static Magnetic-Field-Induced Phase Lag in the Magnetization Response of Tris(dipicolinato)lanthanidesInorganic Chemistry, 2006
- Current-induced resonance and mass determination of a single magnetic domain wallNature, 2004
- Efficient Proton-Templated Synthesis of 18- to 38-Membered Tetraimino(amino)diphenol Macrocyclic Ligands: Structural Features and Spectroscopic PropertiesThe Journal of Organic Chemistry, 2004
- 2MOLCAS as a development platform for quantum chemistry softwareInternational Journal of Quantum Chemistry, 2004
- Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular LevelJournal of the American Chemical Society, 2003